Adsorption and inhibitive effect of N-[(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide on the corrosion of mild steel in HCl medium
DOI:
https://doi.org/10.56919/usci.2324.022Keywords:
Inhibition, adsorption isotherm, SEM, thermodynamicsAbstract
In this study, the inhibitive effects of Schiff’s base, N-[(4{[(Z)-(4-hydroxy phenyl) methylidene] amino} phenyl) sulfonyl acetamide (4-HPMAPSA) on mild steel corrosion in 1.0 M HCl(aq) at different temperatures were investigated using weight loss and scanning electron microscope. The Fourier transform infrared spectrum and X-ray diffraction pattern of 4-HPMAPSA were obtained. It was found that the inhibition effectiveness of 4-HPMAPSA relies on the temperature, 4-HPMAPSA concentration and exposure period. 4-HPMAPSA hinders mild steel corrosion and exhibits a maximum inhibitive efficiency of 88.5 % at 0.5 g of 4-HPMAPSA at 303 K. The activation energy (Ea) value (45.0 to 52.3 kJmol-1) with an average of 47.7 kJmol-1 was obtained for the 4-HPMAPSA-inhibited reaction and 35.1 kJmol-1 for the uninhibited. The thermodynamic values calculated for the 4-HPMAPSA-inhibited reaction show that the process is spontaneous and endothermic. With an R2 value of 0.9646 to 0.9999, Langmuir isotherm best described the 4-HPMAPSA uptake behaviour.
References
Abdallah, M. & AL Jahdaly, B.A., (2015). Gentamicin, Kanamycin and Amikacin Drugs as Non-Toxic Inhibitors for Corrosion of Aluminum in 1.0M Hydrochloric Acid, Int. J. Electrochem. Sci., 10, 9808 – 9823. DOI: https://doi.org/10.1016/S1452-3981(23)11221-1
Abdallaha, M., Zaafaranya, I.A. & AL Jahdalya, B.A. (2016). Corrosion Inhibition of Zinc in Hydrochloric Acid using some Antibiotic Drugs, J. Mater. Environ. Sci. 7 (4), 1107-1118.
Ameh, P.O., (2018). Electrochemical and computational study of gum exudates from Canarium schweinfurthii as green corrosion inhibitor for mild steel in HCl solution, 783-795 DOI: https://doi.org/10.1080/16583655.2018.1514147
Aslam, R., Mobin, M., Zehra, S., Obot, I.B. & Ebenso, E.E. (2017). Dialkylcystine Gemini and Monomeric -Alkyl Cysteine Surfactants as Corrosion Inhibitors on Mild Steel Corrosion in 1 M HCl Solution: A Comparative Study, ACS Omega, 2(9). DOI: https://doi.org/10.1021/acsomega.7b00501
Asmara, Y. P. & Kurniawan, T. (2018). Corrosion prediction for corrosion rate of carbon steel in oil and gas environment: A review. Indones. J. Sci. Technol. 3, 64–74. DOI: https://doi.org/10.17509/ijost.v3i1.10808
Betti, N.,.Al-Amiery, A., KhalidAl-Azzawi, W. & Isahak, W,N. (2023). Corrosion inhibition properties of schif base derivative against mild steel in HCl environment complemented with DFT investigations. Nature Scientifc Reports (2023) 13:8979. DOI: https://doi.org/10.1038/s41598-023-36064-w
Burakov, A.E., Galunin, E.V., Burakova, I.V., Kucherova, A.E., Agarwal, S., Tkachev, A.G. & Gupta, V.K. (2018). Ecotoxicology and environmental safety adsorption of heavy metals on conventional and nanostructured materials for wastewater treatment purposes: a review, Ecotoxicol. Environ. Saf. 148, 702–712 . DOI: https://doi.org/10.1016/j.ecoenv.2017.11.034
Chahul, H.F., Ndukwe, G.I. & Ogwu, D.O. (2018). A thermometric study on the kinetics of the acid dissolution of aluminium in the presence of Napoleonaea imperialis seeds extract and iodide ions, Ovidius University Annals of Chemistry, 29(2): 103-109. DOI: https://doi.org/10.2478/auoc-2018-0015
Eddy, N.O. & Ameh, P.O. (2021). Computational and experimental study on Tapinanthus bangwensis leaves as corrosion inhibitor for mild steel and Al in 0.1 M HCl. Current Topics in Electrochemistry Vol. 23, 2021.
Ekuma, F.K., Ogueji, C. & Okoyeagu, A. (2017). Zinc corrosion inhibition by 4-hydroxyl phenyl methylidene-2-(1-phenyl ethylidene) hydrazine carbothioamide (4-HPMHC) and 4-hydroxy phenyl [methylidene] amino-3, 4- dimethyl-5-phenyl cyclo pent-2-en-1-one (4-HPMCP), J. Chem. Soc. Nigeria, 42(2), 5-10.
Gupta, V.K., Carrott, P.J.M., Singh, R., Chaudhary, M. & Kushwaha, S. (2016). Bioresource Technology Cellulose: a review as natural, modified and activated carbon adsorbent, Bioresour. Technol. 216, 1066–1076. . DOI: https://doi.org/10.1016/j.biortech.2016.05.106
Guruprasada, A.M., Sachinb, H.P., Swethab, G.A. & Prasannad, B.M. (2020). Corrosion inhibition of zinc in 0.1 M hydrochloric acid medium with clotrimazole: Experimental, theoretical and quantum studies. Surfaces and Interfaces, 19 (2020) 100478. . DOI: https://doi.org/10.1016/j.surfin.2020.100478
Hegazy, M.A., Abdallah, M., Awad, M.K. & Rezk, M. (2014). Part I: Experimental Results, Corros. Sci., 81, 54. DOI: https://doi.org/10.1016/j.corsci.2013.12.010
Ikeuba, A.I. & Okafor, P.C. (2019). Green corrosion protection for mild steel in acidic media: saponins and crude extracts of Gongronema latifolium. Pigment & Resin Technology, 48(1):57-64. DOI: https://doi.org/10.1108/PRT-03-2018-0020
Ikeuba, A.I., Ita, B.I., Etiuma, R.A., Bassey, V.M., Ugi, B.U. & Kporokpo, E.B. (2015). Green Corrosion Inhibitors for Mild Steel in H2SO4 Solution: Flavonoids of Gongronema latifolium, Chemical and Process Engineering Research, 34, www.iiste.org ISSN 2224-7467 (Paper), ISSN 2225-0913 (Online).
Jagadeesan, S., Sowmiya, M., Sounthari, P., Parameswari, K., Chitra, S., Senthilkumar, K., 2016. N-heterocycles as corrosion inhibitors for mild steel in acid medium, Journal of Molecular Liquids, 216:42-52. DOI: https://doi.org/10.1016/j.molliq.2015.12.096
Kadhum, A.H., Mohamad,A.B., Hammed, LA., Al-Amiery, A.A., San, N.H. & Musa, A.Y. (2014). Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by New Coumarin, Material, 7, 4335-4348, DOI: https://doi.org/10.3390/ma7064335
Kavitha, V. & Gunavathy, N. (2014). Evaluation of Daucus carota aerial extract as corrosion inhibitor for mild steel in hydrochloric acid medium, International Journal of Research in Advent Technology, 2(7) 146- 154.
Kumari, P., Rao, S.A., & Shetty, P. (2014). Corrosion inhibition of mild steel in 2 M HCl by Schiff base derivative. Procedia material science, 5:499-507. DOI: https://doi.org/10.1016/j.mspro.2014.07.293
Lai, C., Xie, B., Zou, L., Zheng, X. & Ma, X. (2017). Adsorption and Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution by S-allyl-O,O'-dialkyldithiophosphates, 7, DOI: https://doi.org/10.1016/j.rinp.2017.09.012
Ma, J., Zhou, L., Dan, W., Zhang, H., Shao, Y., Bao, C. & Jing, L. (2015). Novel magnetic porous carbon spheres derived from chelating resin as a heterogeneous Fenton catalyst for the removal of methylene blue from aqueous solution, J. Colloid Interface Sci, 446, 298–306 . DOI: https://doi.org/10.1016/j.jcis.2015.01.036
Nwanji, O.L., Omorogie, M.O., Olowoyo, J. O. & Babalola, J.O. (2020). "Remediation of industrial dye by Fentonactivated biogenic waste, Surfaces and Interfaces, 20, 100555. . DOI: https://doi.org/10.1016/j.surfin.2020.100555
Ofuyekpone, O.D., Utub, O.G. & Onyekp, B.O. (2021). Corrosion inhibition for alloy 304L (UNS S30403) in H2SO4 1M solution by Centrosema pubescens leaves extract. Applied Surface Science Advances, 3(2021) 100061. DOI: https://doi.org/10.1016/j.apsadv.2021.100061
Omorogie, M.O., Babalola, J.O., Unuabonah, E.I. & Gong, J.R. (2014). Solid phase extraction of hazardous metals from aqua system by nanoparticle-modified agrowaste composite adsorbents. J Environ Chem Eng, 2(1), 675–684. DOI: https://doi.org/10.1016/j.jece.2013.11.007
Omorogie, M.O., Babalola, J.O., Unuabonah,E.I. & Gong, J.R. (2014). Hybrid materials from agro-waste and nanoparticles: implications on the kinetics of the adsorption of inorganic pollutants. Environ Technol, 35(5), 611–619. DOI: https://doi.org/10.1080/09593330.2013.839747
Onwu, F.K., Ogueji, C. & Mgbemena, N.M. (2016). Inhibition of Corrosion of Zinc in H2SO4 Medium by the Schiff Base, 4-Hydroxy Phenyl Methylidene-2-(l-Phenyl Ethylidene) Hydrazine Carbothioamide (4-HPMHC), DerChemica Sinica, 7(4), 13-20.
Oyedeko, K., Lasisi, M., & Akinyanju, A. (2022). Study of Blend of Extracts from Bitter Leaf (Vernonia Amygdalina) Leaves and Banana (Musa Acuminata) Stem as Corrosion Inhibitor of Mild steel in Acidic Medium. Eur J Eng Technol Res., 7(1), pp. 1–9. DOI: https://doi.org/10.24018/ej-eng.2022.7.1.2708
Pathak, R. K. & Pratiksha, M. (2016). Drugs as corrosion inhibitors: a review, Int. J. Sci. Res. 5 (4) (2016) 671–677. DOI: https://doi.org/10.21275/v5i4.NOV162623
Paul, P.K., Mehta, R.K., Yadav, M. & Obot, I.B. (2021). Theoretical, electrochemical and computational inspection for anti-corrosion activity of triazepine derivatives on mild steel in HCl medium. Journal of Molecular Liquids. DOI: https://doi.org/10.1016/j.molliq.2021.118075
Salman, T. et al., 2019. Novel ecofriendly corrosion inhibition of mild steel in strong acid environment: Adsorption studies and thermal effects. Int J Corros Scale Inhib., 8(4), pp. 1123–1137. DOI: https://doi.org/10.17675/2305-6894-2019-8-4-19
Shah, N.S., Ali, J., Sayed, M., Ul, Z., Khan, H., Iqbal, J. & Arshad, S. (2020). Synergistic effects of H2O2 and S2O8 2− in the gamma radiation induced degradation of congo-red dye: kinetics and toxicities evaluation, Sep. Purif. Technol. 233 (2020) 115966 . DOI: https://doi.org/10.1016/j.seppur.2019.115966
Sharma, A., (2015). Azadirachta indica (Neem) leaf powder as a biosorbent for removal of Cd(II) from aqueous medium, Journal of Hazardous Materials, 125(1-3), 102- 112. DOI: https://doi.org/10.1016/j.jhazmat.2005.05.012
Ugwuja, C.G., Adelowo, O., Ogunlaja, A., Omorogie, M.O., Olukanni, O., Ikhimiukor, O., Iermak, I., Kolawole, G., Guenter, C. & Taubert, A. (2019). Visible-light mediated photodynamic water disinfection@ bimetallic doped hybrid clay nanocomposites, ACS Appl Mater Interfaces 11(28), 25483–25494. DOI: https://doi.org/10.1021/acsami.9b01212
Wanees, A. S.; Radwan, A. B.; Alsharif, M. A. & Abd El Haleem, S. M. (2017). Initiation and Inhibition of Pitting Corrosion on Reinforcing Steel under Natural Corrosion Conditions. Mater. Chem. Phys. 2017, 190, 79–95. . DOI: https://doi.org/10.1016/j.matchemphys.2016.12.048
Wanees, S.A., & Seda, S. H. (2019). Corrosion inhibition of zinc in aqueous acidic media using a novel synthesised Schiff base – an experimental and theoretical study. Journal of Dispersion Science and Technology,
Zhou, L., Ma, J., Zhang, H., Shao, Y. & Li, Y. (2015). Fabrication of magnetic carbon composites from peanut shells and its application as a heterogeneous Fenton catalyst in removal of methylene blue, Appl. Surf. Sci. 324, 490–498. DOI: https://doi.org/10.1016/j.apsusc.2014.10.152
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